内容简介
PART Ⅰ ELEMENTARY PRINCIPLES AND APPLICATIONS TO PROBLEMS IN ONE DIMENSION
1 Review of Concepts of Classical Mechanics
1.1 Generalized or “Good” Coordinates
1.2 Energy,the Hamiltonian,and Angular Momentum
1.3 The State of a System
1.4 Properties of the One-Dimensional Potential Function
2 Historical Review: Experiments and Theories
2.1 Dates
2.2 The Work of Planck. Blackbody Radiation
2.3 The Work of Einstein. The Photoelectric Effect
2.4 The Work of Bohr. A Quantum Theory of Atomic States
2.5 Waves versus Particles
2.6 The de Broglie Hypothesis and the Davisson-Germer Experiment
2.7 The Work of Heisenberg. Uncertaintu as a Cornerstone of Natural Law
2.8 The Work of Born. Probabiliry Waves
2.9 Semiphilosophical Epilogue to Chapter 2
3 The Postulates of Quantum Mechanics. Operators,Eigenfunctions,and Eigenvalues
3.1 Observables and Operators
3.2 Measurement in Quantum Mechanics
3.3 The State Function and Expectation Values
3.4 Time Development of the State Function
3.5 Solution to the Initial-Value Problem in Quantum Mechanics
4 Preparatory Concepts. Function Spaces and Hermitian Operators
4.1 Particle in a Box and Further Remarks on Normalization
4.2 The Bohr Correspondence Principle
4.3 Dirac Notation
4.4 Hilbert Space
4.5 Hermitian Operators
4.6 Properties of Hermitian Operators
5 Superposition and Compatible Observables
5.1 The Superposition Principle
5.2 Commutator Relations in Quantum Mechanics
5.3 More on the Commutator Theorem
5.4 Commutator Relations and the Uncertainty Principle
5.5 “Complete” Sets of Commuting Observables
6 Time Development,Conservation Theorems,and Parity
6.1 Time Development of State Functions
6.2 Time Development of Expectation Values
6.3 Conservation of Energy,Linear and Angular Momentum
6.4 Conservation of Parity
7 Additional One-Dimensional Problems. Bound and Unbound States
7.1 General Properties of the One-Dimensional Schrodinger Equation
7.2 The Harmonic Oscillator
7.3 Eigenfunctions of the Harmonic Oscillator Hamiltonian
7.4 The Harmonic Oscillator in Momentum Space
7.5 Unbound States
7.6 One-Dimensional Barrier Problems
7.7 The Rectangular Barrier. Tunneling
7.8 The Ramsauer Effect
7.9 Kinetic Properties of a Wave Packet Scattered from a Potential Barrier
7.10 The WKB Approximation
7.11 Principle of Least Action and Feyntnan’s Path Integral Formulation
8 Finite Potential Well,Periodic Lattice,and Some Simple Problems with Two Degrees of Freedom
8.1 The Finite Potential Well
8.2 Periodic Lattice. Energy Gaps
8.3 Standing Waves at the Band Edges
8.4 Brief Qualitative Description of the Theory of Conduction in Solids
8.5 Two Beads on a Wire and a Particle in a Two-Dimensional Box
8.6 Two-Dimensional Harmonic Oscillator
8.7 Linear Combination of Atomic Orbitals (LCAO) Approximation
8.8 Density of States in Various Dimensions
PART Ⅱ FURTHER DEVELOPMENT OF THE THEORY AND APPLICATIONS TO PROBLEMS IN THREE DIMENSIONS
9 Angular Momentum
9.1 Basic Properties
9.2 Eigenvalues of the Angular Momentum Operators
9.3 Eigenfunctions of the Orbital Angular Momentum Operators L2 and Lz
9.4 Addition of Angular Momentum
9.5 Total Angular Momentum for Two or More Electrons
10 Problems in Three Dimensions
10.1 The Free Particle in Cartesian Coordinates
10.2 The Free Particle in Spherical Coordinates
10.3 The Free-Particle Radial Wavefunction
10.4 A Charged Particle in a Magnetic Field
10.5 The Two-Particle Problem
10.6 The Hydrogen Atom
10.7 Elementary Theory of Radiation
10.8 Thomas-Fermi Model
11 Elements of Matrix Mechanics. Spin Wavefunctions
11.1 Basis and Representations
11.2 Elementary Matrix Properties
11.3 Unitary and Similariry Transformations in Quantum Mechanics
11.4 The Energy Representation
11.5 Angular Momentum Matrices
11.6 The Pauli Spin Matrices
11.7 Free-Particle Wavefunctions,Including Spin
11.8 The Magnetic Moment of an Electron
11.9 Precession of an Electron in a Magnetic Field
11.10 The Addition of Two Spins
11.11 The Density Matrix
11.12 Other “Pictures” in Quantum Mechanics
11.13 Polarization States. EPR Revisited
11.14 The Transfer Matrix
12 Application to Atomic,Molecular,Solid-State,and Nuclear Physics. Elements of Quantum Statistics
12.1 The Total Angular Momentum,J
12.2 One-Electron Atoms
12.3 The Pauli Principle
12.4 The Periodic Table
12.5 The Slater Determinant
12.6 Application of Symmetrization Rules to the Helium Atom
12.7 The Hydrogen and Deuterium Molecules
12.8 Brief Description of Quantum Models for Superconductivity and Superfluidity
12.9 Impurity Semiconductors and the p-n Junction
12.10 Elements of Nuclear Physics. The Deuteron and Isospin
13 Perturbation Theory
13.1 Time-Independent,Nondegenerate Perturbation Theory
13.2 Time-Independent,Degenerate Perturbation Theory
13.3 The Stark Effect
13.4 The Nearly Free Electron Model
13.5 Time-Dependent Perturbation Theory
13.6 Harmonic Perturbation
13.7 Application of Harmonic Perturbation Theory
13.8 Selective Perturbations in Time
13.9 Atom-Radiation Interaction
13.10 Hartree-Fock Model
14 Scattering in Three Dimensions
14.1 Partial Waves
14.2 S-Wave Scattering
14.3 Center-of-Mass Frame
14.4 The Born Approximation
14.5 Atomic-Radiative Absorption Cross Section
14.6 Elements of Formal Scattering Theory. The Lippmatm-Schwinger Equation
15 Relativistic Quantum Mechanics
15.1 Preliminary Remarks
15.2 Klein-Gordon Equation
15.3 Dirac Equation
15.4 Electron Magnetic Moment
15.5 Covariant Description
16 Quantum Computing
16.1 Binary Number System
16.2 Logic Gates
16.3 Turing Machine and Complexity Classes
16.4 Qubits and Quantum Logic Gates
List of Symbols
APPENDIXES
A Additional Remarks on the x and p Representations
B Spin and Statistics
C Representations of the Delta Function
D Differential Vector Relations
E Harmonic Oscillator in Spherical Coordinates
F Physical Constants and Equivalence Relations
Index