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Chapter 0 The Subject of Transport Phenomena
Part Ⅰ Momentum TransportChapter 1 Viscosity and the Mechanisms of Momentum Transport
1.1 Newton's Law of Viscosity(Molecular Momentum Transport)
Ex.1.1-1 Calculation of Momentum Flux
1.2 Generalization of Newton's Law of Viscosity
1.3 Pressure and Temperature Dependence of Viscosity
Ex.1.3-1 Estimation of Viscosity from Critical Properties
1.4 Molecular Theory of the Viscosity of Gases at Low Density
Ex.1.4-1 Computation of the Viscosity of a Gas Mixture at Low Density
Ex.1.4-2 Prediction of the Viscosity of a Gas Mixture at Low Density
1.5 Molecular Theory of the Viscosity of Liquids
Ex.1.5-1 Estimation of the Viscosity of a Pure Liquid
1.6 Viscosity of Suspensions and Emulsions
1.7 Convective Momentum Transport
Questions for Discussion
Problems
Chapter 2 Shell Momentum Balances and Velocity Distributions in Laminar Flow
2.1 Shell Momentum Balances and Boundary Conditions
2.2 Flow of a Falling Film
Ex.2.2-1 Calculation of Film Velocity
Ex.2.2-2 Falling Film with Variable Viscosity
2.3 Flow Through a Circular Tube
Ex.2.3-1 Determination of Viscosity from Capillary Flow Data
Ex.2.3-2 Compressible Flow in a Horizontal Circular Tube
2.4 Flow through an Annulus
2.5 Flow of Two Adjacent Immiscible Fluids
2.6 Creeping Flow around a Sphere
Ex.2.6-1 Determination of Viscosity from the Terminal Velocity of a Falling Sphere
Questions for Discussion
Problems
Chapter 3 The Equations of Change for Isothermal Systems
3.1 The Equation of Continuity
Ex.3.1-1 Normal Stresses at Solid Surfaces for Incompressible Newtonian Fluids
3.2 The Equation of Motion
3.3 The Equation of Mechanical Energy
3.4 The Equation of Angular Momentum
3.5 The Equations of Change in Terms of the Substantial Derivative
Ex.3.5-1 The Bernoulli Equation for the Steady Flow of Inviscid Fluids
3.6 Use of the Equations of Change to Solve Flow Problems
Ex.3.6-1 Steady Flow in a Long Circular Tube
Ex.3.6-2 Falling Film with Variable Viscosity
Ex.3.6-3 Operation ofa Couette Viscometer
Ex.3.6-4 Shape of the Surface of a Rotating Liquid
Ex.3.6-5 Flow near a Slowly Rotating Sphere
3.7 Dimensional Analysis of the Equations of Change
Ex.3.7-1 Transverse Flow around a Circular Cylinder
Ex.3.7-2 Steady Flow in an Agitated Tank
Ex.3.7-3 Pressure Drop for Creeping Flow in a Packed Tube
Questions for Discussion
Problems
Chapter 4 Velocity Distributions with More than One Independent Variable
4.1 Time-Dependent Flow of Newtonian Fluids
Ex.4.1-1 Flow near a Wall Suddenly Set in Motion
Ex.4.1-2 Unsteady Laminar Flow between Two Parallel Plates
Ex.4.1-3 Unsteady Laminar Flow near an Oscillating Plate
4.2 Solving Flow Problems Using a Stream Function
Ex.4.2-1 Creeping Flow around a Sphere
4.3 Flow of Inviscid Fluids by Use of the Velocity Potential
Ex.4.3-1 Potential Flow around a Cylinder
Ex.4.3-2 Flow into a Rectangular Channel
Ex.4.3-3 Flow near a Corner
4.4 Flow near Solid Surfaces by Boundary-Layer Theory
Ex.4.4-1 Laminar Flow along a Flat Plate(Approximate Solution)
Ex.4.4-2 Laminar Flow along a Flat Plate(Exact Solution)
Ex.4.4-3 Flow near a Corner
Questions for Discussion
Problems
Chapter 5 Velocity Distributions in Turbulent Flow
5.1 Comparisons of Laminar and Turbulent Flows
5.2 Time-Smoothed Equations of Change for Incompressible Fluids
5.3 The Time-Smoothed Velocity Profile near a Wall
5.4 Empirical Expressions for the Turbulent Momentum Flux
Ex.5.4-1 Development of the Reynolds Stress Expression in the Vicinity of the Wall
5.5 Turbulent Flow in Ducts
Ex.5.5-1 Estimation of the Average Velocity in a Circular Tube
Ex.5.5-2 Application of Prandtl's Mixing Length Formula to Turbulent Flow in a Circular Tube
Ex.5.5-3 Relative Magnitude of Viscosity and Eddy Viscosity
5.6 Turbulent Flow in Jets
Ex.5.6-1 Time-Smoothed Velocity Distribution in a Circular Wall Jet
Questions for Discussion
Problems
Chapter 6 Interphase Transport in Isothermal Systems
6.1 Definition of Friction Factors
6.2 Friction Factors for Flow in Tubes
Ex.6.2-1 Pressure Drop Required for a Given Flow Rate
Ex.6.2-2 Flow Rate for a Given Pressure Drop
6.3 Friction Factors for Flow around Spheres
Ex.6.3-1 Determination of the Diameter of a Falling Sphere
6.4 Friction Factors for Packed Columns
Questions for Discussion
Problems
Chapter 7 Macroscopic Balances for Isothermal Flow Systems
7.1 The Macroscopic Mass Balance
Ex.7.1-1 Draining of a Spherical Tank
7.2 The Macroscopic Momentum Balance
Ex.7.2-1 Force Exerted by a 1et (Part a)
7.3 The Macroscopic Angular Momentum Balance
Ex.7.3-1 Torque on a Mixing Vessel
7.4 The Macroscopic Mechanical Energy Balance
Ex.7.4-1 Force Exerted by a Jet(Part b)
7.5 Estimation of the Viscous Loss
Ex.7.5-1 Power Requirement for Pipeline Flow
7.6 Use of the Macroscopic Balances for Steady-State Problems
Ex.7.6-1 Pressure Rise and Friction Loss in a Sudden Enlargement
Ex.7.6-2 Performance of a Liquid-Liquid Ejector
Ex.7.6-3 Thrust on a Pipe Bend
Ex.7.6-4 The Impinging Jet
Ex.7.6-5 Isothermal Flow of a Liquid through an Orifice
7.7 Use of the Macroscopic Balances for Unsteady-State Problems
Ex.7.7.1 Acceleration Effects in Unsteady Flow from a Cylindrical Tank
Ex.7.7-2 Manometer Oscillations
7.8 Derivation of the Macroscopic Mechanical Energy Balance
Questions for Discussion
Problems
Chapter 8 Polymeric Liquids
8.1 Examples of the Behavior of Polymeric Liquids
8.2 Rheometry and Material Functions
8.3 Non-Newtonian Viscosity and the Generalized Newtonian Models
Ex.8.3-1 Laminar Flow of an Incompressible Power-Law Fluid in a Circular Tube
Ex.8.3-2 Flow of a Power-Law Fluid in a Narrow Slit
Ex.8.3-3 Tangential Annular Flow of a Power-Law Fluid
8.4 Elasticity and the Linear Viscoelastic Models
Ex.8.4-1 Small-Amplitude Oscillatory Motion
Ex.8.4-2 Unsteady Viscoelastic Flow near an Oscillating Plate
8.5 The Corotational Derivatives and the Nonlinear Viscoelastic Models
Ex.8.5-1 Material Functions for the Oldroyd 6-Constant Model
8.6 Molecular Theories for Polymeric Liquids
Ex.8.6-1 Material Functions for the FENE-P Model
Questions for Discussion
Problems
Part Ⅱ Energy Transport
Chapter 9 Thermal Conductivity and the Mechanisms of Energy Transport
9.1 Fouriers Law of Heat Conduction(Molecular Energy Transport)
Ex.9.1-1 Measurement of Thermal Conductivity
9.2 Temperature and Pressure Dependence of Thermal Conductivity
Ex.9.2-1 Effect of Pressure on Thermal Conductivity
9.3Theory of Thermal Conductivity of Gases at Low Density
Ex.9.3-1 Computation of the Thermal Conductivity of a Monatomic Gas at Low Density
Ex.9.3-2 Estimation of the Thermal Conductivity of a Polyatomic Gas at Low Density
Ex.9.3-3 Prediction of the Thermal Conductivity of a Gas Mixture at Low Density
9.4 Theory of Thermal Conductivity of Liquids
Ex.9.4-1 Prediction of the Thermal Conductivity of a Liquid
9.5 Thermal Conductivity of Solids
9.6 Effective Thermal Conductivity of Composite Solids
9.7 Convective Transport of Energy
9.8 Work Associated with Molecular Motions
Questions for Discussion
Problems
Chapter 10 Shell Energy Balances and Temperature Distributions in Solids and Laminar Flow
10.1 Shell Energy Balances;Boundary Conditions
10.2 Heat Conduction with an Electrical Heat Source
Ex.10.2-1 Voltage Required for a Given Temperature Rise in a Wire Heated by an Electric Current
Ex.10.2-2 Heated Wire with Specified Heat Transfer Coefficient and Ambient Air Temperature
10.3 Heat Conduction with a Nuclear Heat Source
10.4 Heat Conduction with a Viscous Heat Source
10.5 Heat Conduction with a Chemical Heat Source
10.6 Heat Conduction through Composite Walls
Ex.10.6-1 Composite Cylindrical Walls
10.7 Heat Conduction in a Cooling Fin
Ex.10.7-1 Error in Thermocouple Measurement
10.8 Forced Convection
10.9 Free Convection
Questions for Discussion
Problems
Chapter 11 The Equations of Change for Nonisothermal Systems
11.1 The Energy Equation
11.2 Special Forms of the Energy Equation
11.3 The Boussinesq Equation of Motion for Forced and Free Convection
11.4 Use of the Equations of Change to Solve Steady-State Problems
Ex.11.4-1 Steady-State Forced-Convection Heat Transfer in Laminar Flow in a Circular Tube
Ex.11.4-2 Tangential Flow in an Annulus with Viscous Heat Generation
Ex.11.4-3 Steady Flow in a Nonisothermal Film
Ex.11.4-4 Transpiration Cooling
Ex.11.4-5 Free Convection Heat Transfer from a Vertical Plate
Ex.11.4-6 Adiabatic Frictionless Processes in an Ideal Gas
Ex.11.4-7 One-Dimensional Compressible Flow:Velocity,Temperature,and Pressure Profiles in a Stationary Shock Wave
11.5 Dimensional Analysis of the Equations of Change for Nonisothermal Systems
Ex.11.5-1 Temperature Distribution about a Long Cylinder
Ex.11.5-2 Free Convection in a Horizontal Fluid Layer;Formation of Bénard Cells
Ex.11.5-3 Surface Temperature of an Electrical Heating Coil
Questions for Discussion
Problems
Chapter 12 Temperature Distributions with More than One Independent Variable
12.1 Unsteady Heat Conduction in Solids
Ex.12.1-1 Heatingofa Semi-Infinite Slab
Ex.12.1-2 Heatingofa Finite Slab
Ex.12.1-3 Unsteady Heat Conduction near a Wall with Sinusoidal Heat Flux
Ex.12.1-4 Coolingofa Sphere in Contact with a Well-Stirred Fluid
12.2Steady Heat Conduction in Laminar,Incompressible Flow
Ex.12.2-1 Laminar Tube Flow with Constant Heat Flux at the Wall
Ex.12.2-2 Laminar Tube Flow with Constant Heat Flux at the Wall:Asymptotic Solution for the Entrance Region
12.3Steady Potential Flow of Heat in Solids
Ex.12.3-1 Temperature Distribution in a Wall
12.4Boundary Layer Theory for Nonisothermal Flow
Ex.12.4-1 Heat Transfer in Laminar Forced Convection along a Heated Flat Plate(the von Kármán Integral Method)
Ex.12.4-2 Heat Transfer in Laminar Forced Convection along a Heated Flat Plate(Asymptotic Solution for Large Prandtl Numbers)
Ex.12.4-3 Foreed Convection in Steady Three-Dimensional Flow at High Prandtl Numbers
Questions for Discussion
Problems
Chapter 13 Temperature Distributions in Turbulent Flow
13.1 Time-Smoothed Equations of Change for Incompressible Nonisothermal Flow
13.2 The Time-Smoothed Temperature Profile near a Wall
13.3 Empirical Expressions for the Turbulent Heat Flux
Ex.13.3-1 An Approximate Relation for the Wall Heat Flux for Turbulent Flow in a Tube
13.4 Temperature Distribution for Turbulent Flow in Tubes
13.5 Temperature Distribution for Turbulent Flow in Jets
13.6 Fourier Analysis of Energy Transport in Tube Flow at Large Prandtl Numbers
Questions for Discussion
Problems
Chapter 14 Interphase Transport in Nonisothermal Systems
14.1 Definitions of Heat Transfer Coefficients
Ex.14.1-1 Calculation of Heat Transfer Coefficients from Experimental Data
14.2 Analytical Calculations of Heat Transfer Coefficients for Forced Convection through Tubes and Slits
14.3 Heat Transfer Coefficients for Forced Convection in Tubes
Ex.14.3-1 Design of a Tubular Heater
14.4 Heat Transfer Coefficients for Forced Convection around Submerged Objects
14.5 Heat Transfer Coefficients for Forced Convection through Packed Beds
14.6 Heat Transfer Coefficients for Free and Mixed Convection
Ex14.6-1 Heat Loss bu Free Convection from a Horizontal Pipe
14.7 Heat Transfer Coefficients for Condensation of Pure Vapors on Solid Surfaces
Ex.14.7-1 Condensation of Steam on a Vertical Surface
Questions for Discussion
Problems
Chapter 15 Macroscopic Balances for Nonisothermal Systems
15.1 The Macroscopic Energy Balance
15.2 The Macroscopic Mechanical Energy Balance
15.3 Use of the Macroscopic Balances to Solve Steady-State Problems with Flat Velocity Profiles
Ex.15.3-1 The Cooling of an Ideal Gas
Ex.15.3-2 Mixing of Tuo Ideal Gas Streams
15.4 The d-Forms of the Macroscopic Balances
Ex.15.4-1 Parallel-or Counter-Flow Heat Exchangers
Ex.15.4-2 Power Requirement for Pumping a Compressible Fluid through a Long Pipe
15.5 Use of the Macroscopic Balances to Solve Unsteady-State Problems and Problems with Nonflat Velocity Profiles
Ex.15.5-1 Heating ofa Liquid in an Agitated Tank
Ex.15.5-2 Operation ofa Simple Temperature Controller
Ex.15.5-3 Flow of Compressible Fluids through Heat Meters
Ex.15.5-4 Free Batch Expansion of a Compressible Fluid
Questions for Discussion
Problems
Chapter 16 Energy Transport by Radiation
16.1 The Spectrum of Electromagnetic Radiation
16.2 Absorption and Emission at Solid Surfaces
16.3 Planck's Distribution Law,Wien's Displacement Law,and the Stefan-Boltzmann Law
Ex.16.3-1 Temperature and Radiation-Energy Emission of the Sun
16.4 Direct Radiation between Black Bodies in Vacuo at Different Temperatures
Ex.16.4-1 Estimation of the Solar Constant
Ex.16.4-2 Radiant Heat Transfer between Disks
16.5 Radiation between Nonblack Bodies at Different Temperatures
Ex.16.5-1 Radiation Shields
Ex.16.5-2 Radiation and Free-Convection Heat Losses from a Horizontal Pipe
Ex.16.5-3 Combined Radiation and Convection
16.6 Radiant Energy Transport in Absorbing Media
Ex.16.6-1 Absorption ofa Monochromatic Radiant Beam
Questions for Discussion
Problems
Part Ⅲ Mass Transport
Chapter 17 Diffusivity and the Mechanisms of Mass Transport
17.1 Fick's Law of Binary Diffusion(Molecular Mass Transport)
Ex.17.1-1 Diffusion ofHelium through Pyrex Glass
Ex.17.1-2 The Equivalence of DAB and DBA
17.2 Temperature and Pressure Dependence of Diffusivities
Ex.17.2-1 Estimation of Diffusivity at Low Density
Ex.17.2-2 Estimation of Self-Diffusivity at High Density
Ex.17.2-3 Estimation of Binary Diffusivity at High Density
17.3 Theory of Diffusion in Gases at Low Density
Ex.17.3-1 Computation of Mass Diffusivity for Low-Density Monatomic Gases
17.4 Theory of Diffusion in Binary Liquids
Ex.17.4-1 Estimation of Liquid Diffusivity
17.5 Theory of Diffusion in Colloidal Suspensions
17.6 Theory of Diffusion in Polymers
17.7 Mass and Molar Transport by Convection
17.8 Summary of Mass and Molar Fluxes
17.9 The Maxwell-Stefan Equations for Multicomponent Diffusion in Gases at Low Density
Questions for Discussion
Problems
Chapter 18 Concentration Distributions in Solids and Laminar Flow
18.1 Shell Mass Balances;Boundary Conditions
18.2 Diffusion through a Stagnant Gas Film
Ex.18.2-1 Diffusion with a Moving Interface
Ex.18.2-2 Determination of Diffusivity
Ex.18.2-3 Diffusion through a Nonisothermal Spherical Film
18.3 Diffusion with a Heterogeneous Chemical Reaction
Ex.18.3-1 Diffusion with a Slow Heterogeneous Reaction
18.4 Diffusion with a Homogeneous Chemical Reaction
Ex.18.4-1 Gas Absorption with Chemical Reaction in an Agitated Tank
18.5 Diffusion into a Falling Liquid Film(Gas Absorption)
Ex.18.5-1 Gas Absorption from Rising Bubbles
18.6 Diffusion into a Falling Liquid Film(Solid Dissolution)
18.7 Diffusion and Chemical Reaction inside a Porous Catalyst
18.8 Diffusion in a Three-Component Gas System
Questions for Discussion
Problems
Chapter 19 Equations of Change for Multicomponent Systems
19.1 The Equations of Continuity for a Multicomponent Mixture
Ex.19.1-1 Diffusion,Convection,and Chemical Reaction
19.2 Summary of the Multicomponent Equations of Change
19.3 Summary of the Multicomponent Fluxes
Ex.19.3-1 The Partial Molar Enthalpy
19.4 Use of the Equations of Change for Mixtures
Ex.19.4-1 Simultaneous Heat and Mass Transport
Ex.19.4-2 Concentration Profile in a Tubular Reactor
Ex.19.4-3 Catalytic Oxidation of Carbon Monoxide
Ex.19.4-4 Thermal Conductivity of a Polyatomic Gas
19.5 Dimensional Analysis of the Equations of Change for Nonreacting Binary Mixtures
Ex.19.5-1 Concentration Distribution about a Long Cylinder
Ex.19.5-2 Fog Formation during Dehumidification
Ex.19.5-3 Blending of Miscible Fluids
Questions for Discussion
Problems
Chapter 20 Concentration Distributions with More than One Independent Variable
20.1 Time-Dependent Diffusion
Ex.20.1-1 Unsteady-State Evaporation of a Liquid(the“Arnold Problem”)
Ex.20.1-2 Gas Absorption with Rapid Reaction
Ex.20.1-3 Unsteady Diffusion with First-Order Homogeneous Reaction
Ex.20.1-4 Influence of Changing Interfacial Area on Mass Transferat an Interface
20.2 Steady-State Transport in Binary Boundary Layers
Ex.20.2-1 Diffusion and Chemical Reaction in Isothermal Laminar Flow along a Soluble Flat Plate
Ex.20.2-2 Forced Convection from a Flat Plate at High Mass-Transfer Rates
Ex.20.2-3 Approximate Analogies for the Flat Plate at Low Mass-Transfer Rates
20.3 Steady-State Boundary-Layer Theory for Flow around Objects
Ex.20.3-1 Mass Transfer for Creeping Flow around a Gas Bubble
20.4 Boundary Layer Mass Transport with Complex Interfacial Motion
Ex.20.4-1 Mass Transfer with Nonuniform Interfacial Deformation
Ex.20.4-2 Gas Absorption with Rapid Reaction and Interfacial Deformation
20.5 “Taylor Dispersion”in Laminar Tube Flow
Questions for Discussion
Problems
Chapter 21 Concentration Distributions in Turbulent Flow
21.1 Concentration Fluctuations and the Time-Smoothed Concentration
21.2 Time-Smoothing of the Equation of Continuity of A
21.3 Semi-Empirical Expressions for the Turbulent Mass Flux
21.4 Enhancement of Mass Transfer by a First-Order Reaction in Turbulent Flow
21.5 Turbulent Mixing and Turbulent Flow with Second-Order Reaction
Questions for Discussion
Problems
Chapter 22 Interphase Transport in Nonisothermal Mixtures
22.1 Definition of Transfer Coefficients in One Phase
22.2 Analytical Expressions for Mass Transfer Coefficients
22.3 Correlation of Binary Transfer Coefficients in One Phase
Ex.22.3-1 Evaporation from a Freely Falling Drop
Ex.22.3-2 The Wet and Dry Bulb Psychrometer
Ex.22.3-3 Mass Transfer in Creeping Flow through Packed Beds
Ex.22.3-4 Mass Transfer to Drops and Bubbles
22.4 Definition of Transfer Coefficients in Two Phases
Ex.22.4-1 Determination of the Controlling Resistance
Ex.22.4-2 Interaction of Phase Resistances
Ex.22.4-3 Area Averaging
22.5 Mass Transfer and Chemical Reactions
Ex.22.5-1 Estimation of the Interfacial Area in a Packed Column
Ex.22.5-2 Estimation of Volumetric Mass Transfer Coefficients
Ex.22.5-3 Model-Insensitive Correlations for Absorption with Rapid Reaction
22.6 Combined Heat and Mass Transfer by Free Convection
Ex.22.6-1 Additivity of Grashof Numbers
Ex.22.6-2 Free-Convection Heat Transfer as a Source of Forced-Convection Mass Transfer
22.7 Effects of Interfacial Forces on Heat and Mass Transfer
Ex.22.7-1 Elimination of Circulation in a Rising Gas Bubble
Ex.22.7-2 Marangoni Instability in a Falling Film
22.8 Transfer Coefficients at High Net Mass Transfer Rates
Ex.22.8-1 Rapid Evaporation of a Liquid from a Plane Surface
Ex.22.8-2 Correction Factors in Droplet Evaporation
Ex.22.8-3 Wet-Bulb Performance Corrected for Mass-Transfer Rate
Ex.22.8-4 Comparison of Film and Penetration Models for Unsteady Evaporation in a Long Tube
Ex.22.8-5 Concentration Polarization in Ultrafiltration
22.9 Matrix Approximations for Multicomponent Mass Transport
Questions for Discussion
Problems
Chapter 23 Macroscopic Balances for Multicomponent Systems
23.1 The Macroscopic Mass Balances
Ex.23.1-1 Disposal of an Unstable Waste Product
Ex.23.1-2 Binary Splitters
Ex.23.1-3 The Macroscopic Balances and Dirac's Separative Capacity”and“Value Function”
Ex.23.1-4 Compartmental Analysis
Ex.23.1-5 Time Constants and Model Insensitivity
23.2 The Macroscopic Momentum and Angular Momentum Balances
23.3 The Macroscopic Energy Balance
23.4 The Macroscopic Mechanical Energy Balance
23.5 Use of the Macroscopic Balances to Solve Steady-State Problems
Ex.23.5-1 Energy Balances for a Sulfur Dioxide Converter
Ex.23.5-2 Heighht of a Packed-Tower Absorber
Ex.23.5-3 Linear Cascades
Ex.23.5-4 Expansion ofa Reactive Gas Mixture through a Frictionless Adiabatic Nozzle
23.6 Use of the Macroscopic Balances to Solve Unsteady-State Problems
Ex.23.6-1 Start-Up of a Chemical Reactor
Ex.23.6-2 Unsteady Operation of a Packed Column
Ex.23.6-3 The Utility of Low-Order Moments
Questions for Discussion
Problems
Chapter 24 Other Mechanisms for Mass Transport
24.1 The Equation of Change for Entropy
24.2 The Flux Expressions for Heat and Mass
Ex.24.2-1 Thermal Diffusion and the Clusius-Dickel Column
Ex.24.2-2 Pressure Diffusion and the Ultra-centrifuge
24.3 Concentration Diffusion and Driving Forces
24.4 Applications of the Generalized Maxwell-Stefan Equations
Ex.24.4-1 Centrifugation of Proteins
Ex.24.4-2 Proteins as Hydrodynamic Particles
Ex.24.4-3 Diffusion of Salts in an Aqueous Solution
Ex.24.4-4 Departures from Local Electroneutrality:Electro-Osmosis
Ex.24.4-5 Additional Mass-Transfer Driving Forces
24.5 Mass Transport across Selectively Permeable Membranes
Ex.24.5-1 Concentration Diffusion between Preexisting Bulk Phases
Ex.24.5-2 Ultrafiltration and Reverse Osmosis
Ex.24.5-3 Charged Membranes and Donnan Exclusion
24.6 Mass Transport in Porous Media
Ex.24.6-1 Knudsen Diffusion
Ex.24.6-2 Transport from a Binary External Solution
Questions for Discussion
Problems
Postface
Appendices
Appendix A Vector and Tensor Notation
A.1 Vector Operations from a Geometrical Viewpoint
A.2 Vector Operations in Terms of Components
Ex.A.2-1 Proof of a Vector Identity
A.3 Tensor Operations in Terms of Components
A.4 Vector and Tensor Differential Operations
Ex.A.4-1 Proof of a Tensor Identity
A.5 Vector and Tensor Integral Theorems
A.6 Vector and Tensor Algebra in Curvilinear Coordinates
A.7 Differential Operations in Curvilinear Coordinates
Ex.A.7-1 Differential Operations in Cylindrical Coordinates
Ex.A.7-2 Differential Operations in Spherical Coordinates
A.8 Integral Operations in Curvilinear Coordinates
A.9 Further Comments on Vector-Tensor Notation
Appendix B Fluxes and the Equations of Change
B.1 Newton's Law of Viscosity
B.2 Fourier's Law of Heat Conduction
B.3 Fick's(First)Law of Binary Diffusion
B.4 The Equation of Continuity
B.5 The Equation of Motion in Terms of ?
B.6 The Equation of Motion for a Newtonian Fluid with Constantρandμ
B.7 The Dissipation Functionφv for Newtonian Fluids
B.8 The Equation of Energy in Terms of q
B.9 The Equation of Energy for Pure Newtonian Fluids with Constantρand k
B.10 The Equation of Continuity for Speciesαin Terms of jα
B.11 The Equation of Continuity for Species A in Terms of ωA for ConstantρDAB
Appendix C Mathematical Topics
C.1 Some Ordinary Differential Equations and Their Solutions
C.2 Expansions of Functions in Taylor Series
C.3 Differentiation of Integrals(the Leibniz Formula)
C.4 The Gamma Function
C.5 The Hyperbolic Functions
C.6 The Error Function
Appendix D The Kinetic Theory of Gases
D.1 The Boltzmann Equation
D.2 The Equations of Change
D.3 The Molecular Expressions for the Fluxes
D.4 The Solution to the Boltzmann Equation
D.5 The Fluxes in Terms of the Transport Properties
D.6 The Transport Properties in Terms of the Intermolecular Forces
D.7 Concluding Comments
Appendix E Tables for Prediction of Transport Properties
E.1 Intermolecular Force Parameters and Critical Properties
E.2 Functions for Prediction of Transport Properties of Gases at Low Densities
Appendix F Constants and Conversion Factors
F.1 Mathematical Constants
F.2 Physical Constants
F.3 Conversion Factors
Notation
Author Index
Subject Index